The combustion in fired heaters takes place in the burner. The types of burners and how they function are not covered in detail in this section. The amount of heat released can be easily calculated for a gas when we know the composition of the fuel and the heating values of the various components. For liquid fuels, the heating values are obtained by a calorimeter test.
From these values and using the standard combustion equation, we can determine the composition of the flue gas. As an example, the combustion of methane could be stated :
The following Lower Heating Values(LHV) are used in this script:
Component | Btu/lb | Component | Btu/lb | Component | Btu/lb |
CH4 | 21,520 | C2H6 | 20,432 | C3H8 | 19,944 |
N-C4H10 | 19,680 | I-C4H10 | 19,629 | N-C5H12 | 19,517 |
I-C5H12 | 19,478 | C6H14 | 19,403 | CO | 4,347 |
H2 | 51,623 | N2 | 0 | CO2 | 0 |
C | 14,093 | S | 3,983 | C2H4 | 20,295 |
C3H6 | 19,691 | C4H8 | 19,496 | C6H6 | 17,480 |
H2O | 0 | O2 | 0 | H2S | 6,545 |
Disclaimer:
The formulas and correlations presented herein are all in the public domain and are to be used only as a learning tool. Note that any product, process, or technology in this document may be the subject of other intellectual property rights reserved by sponsors or contributors to this site. This publication is provided as is, without any warranty of any kind, either expressed or implied, including, but not limited to, the implied warranties of fitness for a particular purpose, or non-infringement.
The formulas, correlations, and methods presented herein should not be considered as being recommended by or used by the sponsors of this site. The purpose of this site is educational and the methods may or may not be suitable for actual design of equipment. Only a fired heater design engineer is qualified to decide if a calculation or procedure is correct for an application.